Computer Configuration > Administrative Templates > Firefox
Both
HKLM\Software\Policies\Mozilla\WebsiteFilter\Block
If this policy is enabled, you can specify match patterns that indicate sites to be blocked. The match patterns are documented at https://developer.mozilla.org/en-US/Add-ons/WebExtensions/Match_patterns. There is a 1000 entry limit. If this policy is disabled or not configured, no websites are blocked.